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Some people are very sensitive to niacin and cause a flush, it is a harmless nervous system reaction, not a indicator of toxicity or anything worrisome.
Niacin (vitamin B3) side effects of niacin include: mild dizziness; warmth, redness, or tingly feeling under your skin; itching, dry skin; sweating or chills; nausea, diarrhea, belching, gas; muscle pain, leg cramps; sleep problems (insomnia). Niacin can cause flushing, especially when you first begin taking it. Niacin can cause upset stomach and diarrhea. However, all of these side effects tend to fade over time.